You can perform a powerful 2-card combo with this monster and "Tour Guide From the Underworld". Normal Summon "Tour Guide", using her effect to Special Summon "Archfiend Heiress". Then, Special Summon "Archfiend Commander" from your hand, destroying "Heiress" with its effect. The effect of "Heiress" then activates, so search for "Archfiend Palabyrinth". Activate "Palabyrinth" and use its effect to target "Commander" and banish "Tour Guide". Special Summon a second copy of "Commander" and Xyz Summon a Rank 6 monster. If you Summon "Constellar Ptolemy M7", you can use its effect to recover "Heiress" or "Commander" for further advantage.
This card also combos well with "Archfiend Giant" for Rank 6 Xyz Monster potential, as "Giant" can protect itself from being destroyed.
This card works well if you control a Level 6 Archfiend monster on the field, you can tribute it to summon this card and then use it's on tribute summon effect to get the tributed monster back to the field.
This works well it Archfiend Giant as it allows it to use it's effect again if it has been used already.