In episode 142, Axel Brodie uses this card during his duel against Skull Knight. After Axel Special Summons "Volcanic Doomfire", he activates this card to Special Summon four Bomb Tokens to Skull Knight's side of the field as Skull Knight had four unoccupied Monster Card Zones. "Volcanic Doomfire" then attacks and destroys "Lycanthrope". The second effect of "Volcanic Doomfire" then activates, destroying the Bomb Tokens and inflicting 500 damage to Skull Knight for each monster destroyed this way. Since four were destroyed this way, Skull Knight takes 2000 damage and this wins Axel the Duel.
In episode 169, Axel BrodieSets this card during his Duel against Trueman, but did not activate it. Axel intended to activate this card to Special Summon "Bomb Tokens" to Trueman's side of the field during his next turn. He would then activate "Switch Off" to negate the effect of Trueman's "Flame Wall" until the End Phase and switch one Bomb Token to Attack Position. "Volcanic Doomfire" would then attack and destroy the token and activate its second effect to destroy the remaining tokens and inflict 2000 damage to Trueman. When Trueman activates "The Unselected One", Axel was forced to choose on either preventing "Volcanic Doomfire" or "Volcanic Queen" from being destroyed. Axel selects "Volcanic Doomfire", so his set Cards and "Volcanic Queen" are destroyed.