In episode 29, during Jack's Ground Duel against Tetsu Trudge (while the latter was a Shadow Drone and while the former had assistance from Carly Carmine (Jack couldn't use his right arm as it was still healing, so Carly supported Jack by drawing and holding his cards)), Jack is shown sending this card from the top of his Deck to the Graveyard due to the effect of "Shield Worm".
In episode 123, this card appears in a flashback Dragan has when he tells Jack Atlas the last Duel they had was rigged by Rex Goodwin and if he had not been told to lose on purpose, he wouldn't have held back and lost. This card was shown in Jack's hand during his Turbo Duel against Dragan.
In episode 124, this card was shown in Jack's hand during his Turbo Duel against Dragan. In the next episode, Jack activates the final effect of "Burning Rebirth" to send this card from his hand to the Graveyard and send "Burning Rebirth" to the Graveyard in order to revive "Red Nova Dragon". Since "Burning Rebirth" was removed from the field, "Red Dragon Archfiend" is destroyed.
In the first above-mentioned episode, this card is seen in the Atlas Rising video that Team 5D's watches to find out what Dragan meant by his Turbo Duel with Jack being rigged.
Jack uses this card during his Turbo Duel against Yusei Fudo. He Special Summons this card by sending Yusei's "Trick Battle" to the Graveyard. Later Jack Tributes this card in order to activate "Nightmare Archfiends".