In episode 1, Yami Yugi uses this card during his duel against Seto Kaiba. He Sets this card in Defense Position (which occurred off-screen). Kaiba's "Judge Man" then attacks and destroys this card.
In episode 9, this card is seen in Kaiba's computer when he and the computer were searching for the duel arena that Yugi is dueling on. This card was shown being used in a duel that was on an arena that Yugi was not on. Because of that, Kaiba leaves this arena and starts searching through the other arenas.
In episode 43, Yugi, Joey and Mokuba get attacked by Dragon Zombie, Clown Zombie & Armored Zombie, Mokuba and Yugi summon this card and "Dark Magician" respectively to try & destroy them. This card attacks and destroys "Dragon Zombie" while "Dark Magician" attacks and destroys "Clown Zombie" and "Armored Zombie". The zombies then revive themselves and become even stronger than they were previously. Later Joey activates "Shield & Sword" to make the zombies's ATK 0, allowing Yugi's "Dark Magician" to attack and destroy them for good this time.
In episode 109, this card appears in a flashback Leichter has when he explains to Seto that his treachery began when Gozaburo Kaiba gave him a large amount of dollars to test Seto's business skills.