In episode 190, Zigfried uses this card during his duel against Joey Wheeler. He activates this card before the episode ends. In the next episode, this card Special Summons three "Valkyrie Zweite" and one "Valkyrie Erste". Zigfried was intending to use his combo to perform an OTK, but this fails when Joey activates "Hyper Refresh" before the Battle Damage is subtracted from his Life Points. On Zigfried's End Phase, this card's last effect activates, returning all of Zigfried's Valkyries to his Deck.
In episode 194, Zigfried uses this card again during his duel against Seto Kaiba. He uses this card to summon "Valkyrie Zweite", "Valkyrie Erste", and "Valkyrie Dritte" in an attempt to defeat Kaiba in a one turn kill. After the effect of "Valkyrie Zweite" destroys "X-Head Cannon", Zigfried activates the effect of "Valkyrie Erste" to banish "X-Head Cannon" from Kaiba's Graveyard and make the ATK of "Valkyrie Erste" the same as the ATK of "X-Head Cannon". Finally, "Valkyrie Dritte" gains 100 ATK due to a monster being in the Banished Zone. "Valkyrie Zweite" then attacks directly, but Kaiba activates "Negate Attack" to negate the attack and end the Battle Phase. Zigfried then activates "Mischief of the Time Goddess" to go to the Battle Phase of his next turn. "Valkyrie Zweite" then attacks directly, but Kaiba activates "Magical Trick Mirror" to activate "Mischief of the Time Goddess" from Zigfried's Graveyard as Kaiba's card, allowing Kaiba to go directly to the Battle Phase of his next turn. Since "Mischief of the Time Goddess" skipped Zigfried's End Phase, the drawback of this card never occurrs.