In episode 108, Leichter sets this card during his Duel against Seto Kaiba. In the next episode, Kaiba activates "Heavy Storm" to destroy "Solemn Wishes" and "Life Absorbing Machine", but Leichter activates this card to negate the effect of "Heavy Storm". On Leichter's Standby Phase he pays 700 Life Points to keep this card's effects active. On Leichter's next Standby Phase, he destroys this card as he didn't want to pay any Life Points to keep this card active with his Life Points so low.
In episode 189, Rebecca Hawkins uses this card during her Duel against Vivian Wong. When Vivian activates "Mystical Space Typhoon" to destroy Rebecca's "Gravity Bind", Rebecca activates this card to negate the effect of "Mystical Space Typhoon". Rebecca then chains this card's activation with "Scapegoat" which Special Summons 4 Sheep Tokens to the field ("Scapegoat" wasn't negated because the last card that activates resolves first in a Chain). On Rebecca's Standby Phase, she chooses not to pay the Maintenance Cost to keep this card active, so it is destroyed.
This card is also seen in Yugi's explanation on how chaining works (which occurred during Rebecca's Duel with Vivian). Because "Scapegoat" was activated after "Imperial Order" was activated, Yugi's friends were confused on why "Scapegoat" wasn't destroyed when it was activated, so Yugi explained on what happened.