In episode 143, the Supreme King uses this card during his Duel against Axel Brodie. He summons this card via "Super Polymerization". A replay occurs, but due to this card's effect, "Volcanic Doomfire" is forced to attack it. This card then destroys "Volcanic Doomfire", but Axel banishes "Volcanic Counter" from his Graveyard in order to make the Supreme King take the same amount of Battle Damage he takes, ending the Duel in a Draw.
In episode 144, this card is shown in a series of flashbacks Jaden Yuki has when he sees the memories of the Supreme King within his nightmare.
This card is considered as the "ultimate Evil HERO monster" by the episode's name of its debut.