In episode 140, the Supreme King uses this card during his duel against Jim Crocodile Cook. He summons this card via "Super Polymerization". Due to this card's first effect, its ATK became equal to the combined ATK of the Fusion Material Monsters used to Fusion Summon it (which was 4400). This card then attacks directly, defeating Jim.
In episode 144, this card is shown in a series of flashbacks Jaden Yuki has when he sees the memories of the Supreme King within his nightmare.