- In episode 18, Dimitri uses this card during his Duel against Jaden Yuki while the former was using Yugi Muto's Deck. After Jaden activates "A Hero Emerges" to Special Summon "Elemental Hero Bladedge" in an attempt to defeat "Dark Magician", Dimitri activates this card to Tribute "Dark Magician" and Special Summon "Dark Magician of Chaos". "Dark Magician of Chaos" then attacks and destroys "Bladedge". Due to the effect of "Dark Magician of Chaos", "Bladedge" is banished instead of being sent to the Graveyard.
- This card appears in the Japanese ending theme Borderline Battle.
- In the non-canon duel North American WCQ 2014 Special: Astral vs. Yugi, Yugi activates this card, Tributing "Dark Magician" to Special Summon "Dark Magician of Chaos" from the deck.