In episode 108, this card is shown in a flashback Thelonious Viper has when he notes that all the Duel Energy he just got was from the exhibition match between Jaden and Jesse.
In episode 115, Jesse uses this card during his duel against Trapper. When "Infernal Blasthound" attacks directly, Jesse activates "G Force" to Special Summon this card from his hand and make it "Infernal Blasthound's" new attack target, but Trapper activates "Trap Jammer" to negate the effect of "G Force" and destroy it. This causes this card to go back to Jesse's hand. The direct attack then continues. The first effect of "Infernal Blasthound" then activates, destroying this card. This card's last effect then activates, allowing Jesse to place this card in his Spell & Trap Card Zone as a Continuous Spell Card. In the next episode, Jesse sends this card to the Graveyard in order to activate "Rare Value".
In the second above-mentioned episode, this card is shown in a flashback Jesse has when he remembers obtaining the Crystal Beasts from Maximillion Pegasus. Pegasus claims to Jesse that the Crystal Beasts chose him to be their wielder as he could connect his heart to Duel Monster Spirits.
In episode 172, Jesse uses this card during his duel against Jaden while the latter was thinking that Jesse was Trueman (This was due to the darkness from "Arcana Force 0 - The Fool" infecting Jaden's "Polymerization" card). After he Normal Summons this card, Jesse activates "Golden Rule" and equips it to this card. This activates the first effect of "Golden Rule", allowing Jesse to take "Crystal Beast Ruby Carbuncle" and "Crystal Beast Emerald Tortoise" from his Deck and place them in his Spell & Trap Card Zone as Continuous Spell Cards Jesse then activates the second effect of "Golden Rule" to Special Summon "Crystal Beast Amethyst Cat" from his hand. After Jesse sends "Ruby Carbuncle" to the Graveyard in order to activate "Rare Value", this card is destroyed. After Jesse activates "Crystal Spring", he activates this card's effect to return "Emerald Tortoise" to the top of his Deck. On Jaden's next turn, "Elemental HERO Tempest" attacks this card, but Jesse activates "Mine Blast" to send the top five cards of his Deck (which included "Crystal Beast Sapphire Pegasus", "Crystal Beast Amber Mammoth", and "Crystal Beast Emerald Tortoise") to the Graveyard. He then activates "Rainbow Gravity" to Special Summon "Rainbow Dragon" from his Deck, ignoring the summoning conditions. Due to the last effect of "Rainbow Gravity", "Tempest" is forced to attack "Rainbow Dragon" instead of this card. "Rainbow Dragon" then destroys "Tempest". The force of this attack was so strong that it knocked "Polymerization" out of Jaden's Graveyard. This purifies Jaden's "Polymerization" card of the darkness that tainted it. Jaden then sees that he is Dueling Jesse, so the duel is called off, ending with no result.