In episode 92, Kalin Kessler uses this card during his Ground Duel with Yusei Fudo against Lawton. He activates this card to send the top four cards of his Deck to the Graveyard (Lawton notices that one of the cards being sent was "Infernity Des Gunman"), draw one card and place this card on top of his Deck. Later the Duel is interrupted by Barbara and Lawton's henchmen, but Crow Hogan, Jack Atlas, and Sector Security arrive. Lawton activates an explosive to distract his enemies and escape, but Kalin catches up to him. The two of then decide to continue the Duel without Yusei and his cards. Lawton then activates the effect of "Blaster Ogre" to destroy "Infernity Doom Dragon" and inflict half its ATK as damage to Kalin, but Kalin activates the effect of "Infernity Des Gunman" and "Infernity Climber" from his Graveyard. First Kalin activates the effect of "Infernity Climber" to place it on top of his Deck. Next Kalin banishes "Infernity Des Gunman" from the Graveyard in order to activate its effect, negating the damage he would take and giving Lawton two choices. The first will allow Kalin to draw a card and reveal it and if it's a monster, Lawton will take damage equal to the damage Kalin takes and all effect damage Kalin takes this turn will be inflicted to Lawton instead. If it's not a monster, Kalin will take damage equal to the damage he took this turn. The second choice will allow Lawton to negate the effect of "Infernity Des Gunman", but Kalin won't take any effect damage this turn. Lawton chooses the first choice as he believes this card to be Kalin's top card, however Kalin reveals that his top card is "Infernity Climber". After he explains how it got on top of his Deck, the effect of "Infernity Des Gunman" activates, inflicting all damage Kalin would have taken to Lawton and winning Kalin the Duel.
This card appears in a flashback Lawton has when he remembers that Kalin's top card was this card and he is positive that if he accepts Kalin's bet and continue the Duel, then he will win.