This card's name is "Amazon Chain Master" in the English dub.
This card has different artwork in the manga.
In episode 91, Mai Valentine uses this card during her Duel against Yami Marik. She summons this card in Attack Position. After Yami Marik summons "Holding Arms", he uses it to attack this card. Due to the effect of "Holding Arms", it is not destroyed and Yami Marik takes no Battle Damage. The second effect of "Holding Arms" then activates, forbidding this card from attacking for three turns. Mai then activates "Grave Arm" to destroy this card. This card's effect then activates, allowing Mai to take Marik's "The Winged Dragon of Ra" from his Deck and add it to her hand.
Zane Truesdale gave this card to the bully dueling Syrus in Episode 7 to insure that the bully would not tell anyone about the duel and that he would stop bullying Syrus. This is only in the dub. In the original the card given was "Breaker the Magical Warrior".